Product ID:ASAHIKLIN 225, 1663
MSDS Date:07/11/1996
FSC:6850
NIIN:00N079161
MSDS Number: CGZBF

TECH SPRAY INC

AMARILLO, TX 79105-0949
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 806-372-8523

Preparer: B. RIFFEL

Cage: DO677

TECH SPRAY INC

949 AMARILLO, TX 79105-0949 US

Telephone: 806-372-8523

Cage: DO677

3,3-DICHLORO-1,1,1,2,2-PENTAFLUOROPROPANE (HCFC-225CA).

CAS: 422-56-0

Fraction By Weight: 40-50%

OSHA PEL N/K

ACGIH TLV: N/K

1,3-DICHLORO-1,1,2,2,3-PENTAFLUOROPROPANE (HCFC-225CB).

CAS: 507-55-1

Fraction By Weight: 50-60%

OSHA PEL N/K

ACGIH TLV: N/K

SHIPPING CONTAINER REQUIRES HCFC WARNING LABEL.

RTECS: 9999999ZZ

SINGLE DOSE

RTECS: 9999999ZZ

INTO LUNGS, WHICH CAN CAUSE CHEM PNEUM & SYSTEMIC

RTECS: 9999999ZZ

IN 28-DAY INHAL STUDIES W/RAT, ACTIVITY &

RTECS: 9999999ZZ

ISOMER. TOX WAS OTHERWISE CONFINED TO LIVER; LIVER

RTECS: 9999999ZZ

FOLLOWING TREATMENT W/EITHER ISOMER. HCFC-226CA WAS

RTECS: 9999999ZZ

EFTS. IN 28-DAY STUDY W/MARMOSET, EXPOS TO HCFC-CA AT

RTECS: 9999999ZZ

DEPOSITION ASSOC W/CHANGES IN SERUM BIOCHEMICAL

RTECS: 9999999ZZ

5,000 PPM CAUSED SOMNOLENCE DURING EXPOS & INCR OF

RTECS: 9999999ZZ

HCFC-225CB. IN ONE STUDY W/MAMMALIAN CELL CULTURES

RTECS: 9999999ZZ

HCFC-225CB ELICITED A MARGINAL RESPONSE.

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY
BE CONTRAINDICATED EXCEPT FOR LI FE-SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CFC'S . INHAL:MAJOR RTE OF EXPOS. VAP
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:IS HVR/AIR & CAN CAUSE SUFFOCATION BY
REDUCING AVAIL OXYG FOR BRTHG. BRTHG HIGH CONCS OF VAP MAY CAUSE LT
HEAD, GIDD, SHORTNESS OF BREATH, CONFUSN & MAY LEAD TO NARCOS, CARD
IRREGS/UNCON. INH AL OF HIGH CONCS IN CLOSELY CONFINED AREA MAY BE
FATAL. EYES:LIQ CONT MAY IRRIT. SKIN:NOT CORR HOWEVER, RPTD/ (ING
5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:CALL MD IMMED . DO NOT INDUCE VOMIT UNLESS DIRECTED BY
MD. INHAL:MOVE TO FRESH AIR IN CASE OF ACCIDENTAL INHAL OF VAPS. IF
VICTIM HAS STOPPED BRTHG, GIVE ARTF RESP. CALL FOR PROMPT MED AT
TN. EYES:FLUSH W/LG AMTS OF WATER FOR AT LST 15 MINS/UNTIL IRRIT
SUBSIDES. IF IRRIT PERSIST, GET MED ATTN. SKIN:REMOVE CONTAM CLTHG
(INCL SHOES) & WASH BEFORE REUSE. FLUSH W/LG AMTS OF WATER.
(SUPDAT)

Flash Point Method:TCC
Flash Point:NON-FLAMMABLE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT . CONTAINERS CAN BUILD PRESSURE & BURST
IN FIRE SITUATION.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE FLUORIDES, CHLORIDES & PHOSGENE . HAZARDOUS COMBUSTION
PRODUCTS:SMOKE, FUMES & OXIDES OF CARBON.

Spill Release Procedures:EVACUATE AREA. VENT AREA WILL & AVOID BRTHG
VAPS. VAP CONC WILL BE HIGHEST ALONG FLOOR & IN LOW LYING AREAS.
PICK UP LIQ ON SUITABLE ABSORB & STORE IN SEALED METAL CNTNRS. SHUT
OFF FIRE SOURCES. WORKE RS SHOULD WEAR PROPER EQUIP TO WORK IN
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AMBIENT STORAGE TEMPERATURE.
ATMOSPHERIC STORAGE PRESSURE. STORE IN COOL, WELL VENTED PLACE OUT
OF DIRECT SUNLIGHT & AWAY FROM INCOMPATIBLE MATLS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF CHLORIDES, FLUORIDES/PHOSGENE . KEEP CNTNR CLSD WHEN NOT IN
USE. FO LLOW ALL MSDS & LBL WARNINGS (SUPP DATA)

Respiratory Protection:IF CONCS ARE OVER EXPOS LIMIT & ARE KNOWN, A
NIOSH APPRVD AIR PURIFYING RESP W/ORGANIC VAPOR CARTRIDGES MAY BE
ACCEPT. REFER TO CARTRIDGES FOR ACCEPT LEVELS. IF CONCS ARE OVER
EXPOS LIMIT & ARE UNKNOW N, USE A NIOSH APPRVD SUPPLIED AIR RESP.
Ventilation:LOCAL EXHAUST VENT ACCEPTABLE. MECHANICAL VENT RECOMMENDED.
DO NOT USE IN CONFINED SPACE W/OUT MECHANICAL VENT EQUIP.
Protective Gloves:SOLVEX, BUTYL GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC:USE SOAP IF AVAIL. IF IRRIT PERSISTS, SEEK MED ATTN.
SPILL PROC:CLEAN UP AREA. UNPROTECTED PERSONNEL SHOULD MOVE UPWIND.
OTHER PREC:EVEN AFTER CNTNR IS EMPTIED. HCFC-225CA & HCFC-225CB
ARE LISTED AS SNAP ACCEPT SUBSTITUTES FOR CFC'S IN SOLV CLEANING
APPLICATIONS. THIS PROD IS CLASS II CMPD AS SUCH(ING 4)

Boiling Pt:B.P. Text:129F,54C
Melt/Freeze Pt:M.P/F.P Text:-204F,-131C
Vapor Density:7
VOC Pounds/Gallon:200
Evaporation Rate & Reference:>1 (H*2O=1)
Solubility in Water:<1
Appearance and Odor:CLEAR, WATER-WHITE MOBILE LIQUID W/MILD ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
REACTIVE ALKALI METALS, STRONG ACIDS & BASES.
Stability Condition to Avoid:CONTACT W/OPEN FLAME, HEAT.
Hazardous Decomposition Products:CHLORIDES & FLUORIDES . HYDROGEN
CHLORIDE, PHOSGENE, CHLORINE, CARBON DIOXIDE & CARBON MONOXIDE.

Waste Disposal Methods:FEDERAL, STATE & LOCAL LAWS GOVERNING DISPOSAL
OF MATERIALS CAN DIFFER. ENSURE PROPER DISPOSAL COMPLIANCE W/PROPER
AUTHORITIES BEFORE DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.